Structural studies of L10 FePt nanoparticles

We have studied the lattice parameter changes of L10 FePt nanoparticles annealed to near equilibrium as a function of composition by x-ray diffraction. We have found that the ~111! diffraction peak shifts linearly with composition, however, the c parameter mostly changes in the Pt rich compositions and the a parameter mostly changes in the Fe rich compositions with respect to the equiatomic composition. This causes the tetragonality of the L10 structure to be maximized near the Fe 50%/Pt 50% composition. The magnetic properties were measured at room temperature and at 5 K and are correlated to the structural changes occurring as a function of composition. © 2002 American Institute of Physics. @DOI: 10.1063/1.1507837#